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Cyanotype
Invented
by Sir John Herschel in 1841, this simple process gives a continuous-tone
image of Prussian Blue using a sensitising solution of Ammonium Ferric
Citrate and Potassium Ferricyanide. These iron salts, when exposed to
natural or artificial ultraviolet light, are reduced to their ferrous
state, producing a high contrast blue image when oxidised. Oxidation is
hastened by immersion in running water, which also washes away the unused
iron salts.
The
Process
Solution A 65 g ammonium ferric citrate (green) in distilled water to
make 250ml total.
Solution B 23 g potassium ferricyanide in distilled water to make 250ml
total.
Note : distilled water is more commonly known as 'purified water'.
Store solutions separately in brown glass bottles, away from light. Filter
before use, and mix in equal proportions A to B.
Printing
Paper: For all alternative processes high quality art paper such as those
used in printmaking or watercolour work are most suitable. Atlantis Silversafe
200g/sq m., Somerset Satin and Waterford Satin are good papers to start
with, however it is advisable to make tests to find a paper to suit your
requirements.
Coat in
subdued tungsten light, and dry away from light and heat. Print by contact
(in a printing frame with a full sized negative) in sunlight or by an
ultra-violet light source until the shadows look bronzed. Allow at least
one stop over-exposure to compensate for loss of density during processing.
Development
Immerse in running water, and wash until the chartreuse stain of the ferric
ammonium citrate has completely disappeared. Take care to avoid excessive
washing as this will to wash out the image.
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